Learning, Educating, Achieving, and Retraining for the Nation Act or LEARN Act - Amends the Workforce Investment Act of 1998 to authorize the Secretary of Labor to: (1) make discretionary grants to states, local boards, and federally-recognized tribal organizations for adult on-the-job training or dislocated worker on-the-job training programs; and (2) use up to 10% of funds authorized under this Act to make grants to such entities for developing on-the-job training programs, including providing capacity building activities for local staff.